Questions tagged [electrolysis]

Electrolysis is a phenomenon where dissolved or molten electrolytes (ionic compounds) split-up into other element/ compound substance, due to application of external voltage. Electrolysis has many applications, especially industries.

Electrolysis is a phenomenon, where, on dissolved or molten electrolytes (ionic compounds), voltage is applied from an external source (through electrodes); components of the compounds, i.e. the cations (+ve charged particles) and anions (-ve charged particles) move through the fluid, along an electric field, according to the voltage gradient ((i.e. to neutralize the electrodes. Cations (+) move towards the cathode (the electrode where negative charge is being applied from the exterior) and anions (-) move towards the anode (the electrode where positive charge is being applied from the exterior))). When an ion particle reaches the electrode, it no more becomes neutralized by its counter ion, but by the incoming (at the cathode) or outgoing (at the anode) electrons. As a result, the ion goes through a chemical change into a neutral species, ("released" or "discharged") and usually does not go back to the initial state. (However, from more than one cation or more than one anion, which one will be released depends upon various factors like discharge potential, overvoltages etc.; those again depends upon the ions, the materials used to make the electrode, etc.)

Electrolysis has many applications, including electroplating, element extraction and purification.

However, there is a very common example of electrolysis in day-to-day life, i.e. recharging a rechargeable (secondary) battery cell, which is the reverse reaction of electrochemical cell (battery), where the normal cathode of a battery cell (+ve out) is forcefully converted into an anode (+ve in), and normal anode of a battery cell (-ve out) is forcefully converted into a cathode (-ve in).

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Is there any generalized symbol for an electrolytic or electroplating cell?

Is there any symbol for an electrolytic cell? An electroplating cell, for instance? (There are commonly used symbol for electrochemical cell (battery symbol). But symbol for electrolytic cell not seen. Neither in electricals , nor in electronics…
Always Confused
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Why is my multimeter not measuring current?

I'm doing a little bit of experimentation with a glass of water and a 9 V battery. I added a little bit of salt to the water, and I measure the resistance in the water from probe to probe to be ~60 kΩ. Ohm's law tells me the current (given…
Outis Nemo
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Why do batteries only have resistance one way?

I initially had this question because I was playing around with brine electrolysis and I found that the resistance is 0 one way (positive in negative cell) and infinite the other way (positive in positive cell). I tested it again using a normal AA…
popdog
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The best voltage for corrosion removal electrolysis?

What 'd be the optimum or best voltage value used in a corrosion removal electrolysis?
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Design for a PLL Auto-Locking Circuit

I am looking into electrolysis efficiency using an auto-locking PLL circuit that is supposed to latch onto the resonant frequency of the electrolysis cell, a frequency determined by the inductance of the bifilar coil and the capacitance of the cell…
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How do I calculate the current needed to prevent corrosion on a piece of metal?

Consider I have a piece of aluminum and a caustic bath of some Ph level. If I stick the aluminum in the bath, it will corrode over time depending on the Ph level of the solution. I understand it is possible to prevent corrosion by applying current…
user148298
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Resistor for maximum water electrolysis

I've partaken in an experiment where I am looking to create the most efficient way to conduct water electrolysis. My only need is that I don't trip a breaker. I will be running at 120vac, and likely a 15 amp breaker. I've been looking at…
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AC water sensor for electrolysis

I have 2 electrodes placed in a water bucket for electrolysis, electrode[A], and electrode[B]. I am supplying a positive DC voltage to electrode[A] and connecting electrode[B] to the ground and this polarity changes after half an hour and so…
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Dual-Power Sourcing for 15MW Electrolyser: Wind Farm and Electrical Grid Feasibility

I am part of a team working on a 15MW electrolyser project comprising six 2.5MW containerized electrolysers. This setup will be positioned near a 20MW wind farm, and there is also the potential for us to import an additional 5MW from the local…
Ricardo
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Measuring resistance in corrosion removal electrolysis

I tried to measure the resistance of my electrolysis setup (rusty object on cathode, clean iron anode, electrolyte = 3l H2O + 1tb spoon baking soda). But the resistance fluctuated from 50 to 70 kΩ even when everything was still. During the reading…
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Electrical RC circuit

For a simple RC circuit with a resistor and capacitor in series with a controlled voltage source, the derivation for the voltage across the capacitor and resistor is easy, i.e. substituting current \$I\$ as a derivative of charge \$Q\$ in and…
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Why does the Lichtenberg figure form in one direction?

In videos such as this one, we see that the Lichtenberg figure grows from one side to the other, in this case from the left to the right. Why does the figure not grow from both sides and meet somewhere in the middle?
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Wireless power to achieve water electrolysis

I am trying to transfer power wirelessly through inductive coupling to achieve hydrolysis. When using a transmitter coil, DC powered at 9V, I am able to illuminate an LED connected to the receiver coil. If I snip the LED off and place the exposed…
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How does pulsing current through a better conductor generate more heat?

We are pulsing 20A, 12V current for electrolysis through a 6% KOH solution between two steel plates. Because of steel shortages, we have switched to a steel plate that is very slightly thicker. We are suddenly seeing 40C more heat in the system. …
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Advice for low voltage electrolysis system please

I want to setup a simple electrolysis system with an energy source, two cables, a graphite anode and a steel cathode submerged in sea water. A low voltage of exactly 1.23 V needs to be applied over a couple of weeks with as few interruptions as…
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