You can get UL94V-0 (flame retardant) PLA, at a price. It also generally requires higher temperature for printing.
If you have ordinary PLA it may not be as safe as an inexpensive ABC enclosure, and certainly will have a lower temperature at which it softens.
If you have non-flame-retardant PLA housing, it's a judgment call as to whether your USB could plausibly generate flames under possible fault conditions. The power is adequate to do so. Personally, even with just 5V USB input, I'd be reluctant to do it for something that was powered 24/7 and unattended, and would certainly never give or sell it to someone.
Note: I just did a brief informal test (roughly similar to UL94V-0 testing method) with a brand-name (MG Chemicals) PLA and it does support a vertical flame (burns with a similar blue flame to polyethylene and drips burning plastic) so it would not pass minimum flammability standards for a commercial housing.