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I have a 1.8V circuitry with two parallel capacitors and please let me know how can I setup or find out the impedance across the capacitor C420.

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For this specific case, in which the capacitors are connected to a DC source, their impedance is esentially infinite. It is well known that capacitors act as an open circuit when conected to a DC source. Basically, the electrons try to accumulate on one of the elctrodes but the dielectric gap prevents any significant current from flowing, thus, we consider the capacitors to behave as an open circuit.

We can model the impedance of the capacitor by the following formula (that you may have seen):

formula

Then, since DC sources are essentially a source with 0Hz you can see that the value of Xc, according to the equation, aproaches infinity.