If there is no plastic insulation, then you can use some Junction Temperature Equations \$T_j = T_a + R_{tj}*current*current\$, and you would only need to find out \$R_{tj}\$. Keep in mind that different length's of wire give different \$R_{tj}\$. So measure the one you will be using.
\$T_j\$ = The temperature you heat up to
\$T_A\$ = Room temperature
\$R_{tj}\$ = Thermal resistance of the wire.. which sounds very weird..
In other words, pass through 2 amps, measure the temperature after 10 minutes so it has settled down, The \$R_{tj}\$ would then be equal to \$\frac{measured temp - T_A}{2*2}\$. The measurement should be on a naked copper wire.
It won't be perfect (because the resistance of the wire changes with the temperature), also you will use some plastic insulation which will thermally insulate the wire like jacket so it will get hotter (imagine a dusty heatsink). But it will give you a good approximation.
And... I'm no expert, but in my opinion, heating something with constant current from 10 degrees to 20 degrees goes faster than 110 to 120, because at 110 degrees the temperature bleeds out. So I would make use of a capacitor-discharging approximation. The same way you charge a capacitor, it goes slower and slower until it reaches its final voltage.
So I'll use two approximations, which are just my gut feeling, it will probably put you in the ball park at least. Right now I'm using witch craft.
The voltage across a capacitor with a resistor at its terminals bleeds out according to this equation:
\$V(t) = V_0e^{-\frac{t}{RC}}\$
apply witchcraft and identify the temperatures
\$T(t) = T_je^{-\frac{t}{K}}\$
\$ln(\frac{T(t)}{Tj}) = -\frac{t}{K}\$
\$K = \frac{-t}{ln(\frac{T(t)}{Tj})}\$
\$T_j\$ = The temperature you heat up to
\$T(t)\$ = Temperature at time t since you stopped heating it up
\$t\$ = time t since you stopped heating it up
So heat it up to 50 °C, wait until it reaches 40 °C, t would be the time it took for it to go from 50 to 40 °C in seconds.
\$K = \frac{-t}{ln(\frac{40}{50})}\$
Once we've acquired the K value and the \$R_{tj}\$ value, we're done with the measuring. And the capacitor equation is for discharging, let's change it to charging and get the time it takes until it reaches some dangerous temperature. I'd say 100 °C is dangerous. Paper self ignites at 220°C or is it 210.. whatever. Also your insulation starts melting around 100-200°C.
So, let's go back to this equation:
\$T(t) = T_je^{-\frac{t}{K}}\$
If I'm charging it up, then it's like this:
\$T(t) = T_j(1-e^{-\frac{t}{K}})\$
Now we want to know the t until it reaches 100 °C.
\$100 = T_j(1-e^{-\frac{t}{K}})\$
\$t = -K*ln(1-\frac{100}{T_j}) \$
So say that you measured K to be 50 and calculated \$T_j\$ to 500°C, then it would take \$-50*ln(1-\frac{100}{500})\$ = 11.15 seconds
Keep in mind, I used two approximations that are very approximative, they will put you within the ballpark, they are nowhere near perfect or exact.